量子电子学报, 2003, 20 (3): 287, 网络出版: 2006-05-15
微波放电研究大气中NO+和H3O+(H2O)n离子的形成过程
Study on NO+ and H3O+(H2O)n Ions Formation Dynamics Through Microwave Discharge
摘要
利用微波放电电离质谱装置,分别通过N2与O2、水蒸气与空气的微波放电,产生了大气中存在的NO+和H3O+.(H2O)n离子,动力学过程的分析和讨论表明这几种离子是由大气中的初始反应离子N+2、N+、O+2、O+与周围环境中的原子、分子经过一系列的离子-分子反应产生的.这一结论也同时模拟了大气中NO+和H3O+.(H2O)n的形成过程.
Abstract
By microwave discharge of the mixture of N2 and O2, water vapor and air, the NO+ and H3O+(H2O)n which originally exist in the earth's ionosphere were produced. The dynamics analysis indicates that these ions in the atmosphere are formed by the ion chemistry of the primary ions produced through the cosmic radiation of the air reacting with electrons, atoms and molecules surrounded them. This conclusion has also simulated the formation process of these ions. At the same time, the figures of the mass spectra of the microwave discharge of the mixture of N2, O2 the water vapor and air were also presented.
程平, 王鸿梅, 李建权, 张为俊, 曹德兆, 储焰南. 微波放电研究大气中NO+和H3O+(H2O)n离子的形成过程[J]. 量子电子学报, 2003, 20(3): 287. 程平, 王鸿梅, 李建权, 张为俊, 曹德兆, 储焰南. Study on NO+ and H3O+(H2O)n Ions Formation Dynamics Through Microwave Discharge[J]. Chinese Journal of Quantum Electronics, 2003, 20(3): 287.
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