Frontiers of Optoelectronics, 2014, 7 (1): 37, 网络出版: 2014-07-10  

Hydrazine processed Cu2SnS3 thin film and their application for photovoltaic devices

Hydrazine processed Cu2SnS3 thin film and their application for photovoltaic devices
作者单位
1 School of Science, Changchun University of Science and Technology, Changchun 130022, China
2 Wuhan National Laboratory for Optoelectronics (WNLO), Huazhong University of Science and Technology, Wuhan 430074, China
3 Department of Environmental Science, College of Environmental Sciences, Minzu University of China, Beijing 100081, China
4 School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China
摘要
Abstract
Copper tin sulfide (Cu2SnS3) was a potential earth abundant absorber material for photovoltaic device application. In this contribution, triclinic Cu2SnS3 film with phase pure composition and large grain size was fabricated from a hydrazine solution process using Cu, Sn and S as the precursors. Absorption measurement revealed this Cu2SnS3 film had a direct optical band gap of 0.88 eV, and Hall effect measurement indicated the film was p-type with hole mobility of 0.86 cm2/Vs. Finally Mo/Cu2SnS3/CdS/ZnO/AZO/Au was produced and the best device efficiency achieved was 0.78%. Also, this device showed improved device performance during ambient storage. This study laid some foundation for the further improvement of Cu2SnS3 solar cell.

Jun HAN, Ying ZHOU, Yang Tian, Ziheng HUANG, Xiaohua WANG, Jie ZHONG, Zhe XIA, Bo YANG, Haisheng SONG, Jiang TANG. Hydrazine processed Cu2SnS3 thin film and their application for photovoltaic devices[J]. Frontiers of Optoelectronics, 2014, 7(1): 37. Jun HAN, Ying ZHOU, Yang Tian, Ziheng HUANG, Xiaohua WANG, Jie ZHONG, Zhe XIA, Bo YANG, Haisheng SONG, Jiang TANG. Hydrazine processed Cu2SnS3 thin film and their application for photovoltaic devices[J]. Frontiers of Optoelectronics, 2014, 7(1): 37.

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