中国激光, 2007, 34 (s1): 51, 网络出版: 2009-05-25
强碳化物形成元素在激光原位合成颗粒增强涂层中的作用
Influence of Strong-Carbide-Formation Elements on Laser Producing Fe-Matrix Composite Reinforced by In-Situ Synthesized Particles
材料学 材料加工工程 颗粒增强金属基复合涂层 激光熔覆 激光合金化 强碳化物形成元素 复合添加 materials materials processing engineering particles reinforced metal-matrix composite laser cladding laser alloying strong-carbide-formation elements adding jointly
摘要
不同的强碳化物形成元素对激光制备原位合成颗粒增强复合涂层具有不同的作用。向激光合金化或激光熔覆形成的高碳当量熔池中添加能与碳形成间隙相的某些强碳化物形成元素,有利于获得与基材冶金结合的、具有原位合成特征的复合碳化物颗粒增强的高耐磨复合涂层,并且它们对于增强颗粒的形核与生长发挥着各自不同的作用,其中Ti是最重要的形核元素。最终确定了强碳化物形成元素(Ti+Zr+Mo+WC)复合添加的优化方案。采用优化方案在钢和铸铁表面制备出激光原位合成颗粒增强复合涂层。这种涂层在工业生产中表现出优异的摩擦学特性,而这种技术思路在镍基表面也得到了实现。
Abstract
Adding carbide-formation elements into the high-carbon-equivalent FeCSiB molten pool induced by laser cladding or laser alloying is favorable of the formation of high wearable metal matrix composite coating with multiple carbide particles reinforcement by in-situ synthesizing and with strong metallurgical bond to the substrates. They play different roles in promoting the nucleation and growth of the reinforcement carbides, among which Ti is the most important element for particle nucleation. The adding combination of the strong carbide formation element (Ti+Zr+Mo+WC) was optimized. Tribological tests and application checks in typical key parts approve that the laser produced composite coatings reinforced by in-situ particles demonstrated excellent wear resistance and coupling capability. The above concept on producing in-situ synthesized particles reinforced composite coatings has been successfully used in laser surface strengthening of nickel-base alloy.
马明星, 刘文今, 钟敏霖, 吴朝锋, 张伟明, 张红军. 强碳化物形成元素在激光原位合成颗粒增强涂层中的作用[J]. 中国激光, 2007, 34(s1): 51. 马明星, 刘文今, 钟敏霖, 吴朝锋, 张伟明, 张红军. Influence of Strong-Carbide-Formation Elements on Laser Producing Fe-Matrix Composite Reinforced by In-Situ Synthesized Particles[J]. Chinese Journal of Lasers, 2007, 34(s1): 51.