发光学报, 2010, 31 (4): 585, 网络出版: 2010-08-31
稀土配合物Eu(DBM)3phen/聚丙烯复合薄膜的光学性质
Optical Spectra of Thin Composite Eu(DBM)3phen/Polypropylene Film
摘要
制备了Eu(DBM)3phen掺杂的聚丙烯(PP)薄膜复合材料。利用发光光谱技术, 分别展示了Eu(DBM)3phen和Eu(DBM)3phen/PP薄膜的稳态光致发光光谱, 比较了这两种材料的发光寿命。与纯的Eu(DBM)3phen相比, 该复合材料的发光稳定性有较大的提高; 观察到了折射率边界对Eu3+自发辐射速率的影响。
Abstract
Eu(DBM)3phen complex were synthesized and introduced into polypropylene (PP), obtaining the composite Eu(DBM)3phen/PP film with smooth surface and transparency. Room-temperature spectroscopy and decay dynamics were performed to explore the luminescence properties of Eu(DBM)3phen and Eu(DBM)3phen/PP film. The results indicated that the Eu(DBM)3phen/PP film displays strong characteristic luminescence and interesting decay lifetime of the Eu3+ ions. Furthermore,the luminescence of Eu-(DBM)3phen/PP film exhibits an improved thermal stability compared with Eu(DBM)3phen.
叶钊, 段佩华, 张继森, 骆永石, 吕少哲, 张立国, 任建岳. 稀土配合物Eu(DBM)3phen/聚丙烯复合薄膜的光学性质[J]. 发光学报, 2010, 31(4): 585. YE Zhao, DUAN Pei-hua, ZHANG Ji-sen, LUO Yong-shi, LU Shao-zhe, ZHANG Li-guo, REN Jian-yue. Optical Spectra of Thin Composite Eu(DBM)3phen/Polypropylene Film[J]. Chinese Journal of Luminescence, 2010, 31(4): 585.