光学学报, 2011, 31 (11): 1116001, 网络出版: 2011-10-17
Li+与Er3+共掺Y2O3纳米晶体上转换发光增强研究
Enhancement of Upconversion Luminescence in Li+ Codoping Er3+:Y2O3 Nanocrystals
摘要
研究了Li+和Er3+共掺Y2O3纳米晶体粉末的上转换发光特性,并重点分析了Li+的掺杂浓度对粉末晶形结构和发光强度的影响。结果表明,采用燃烧法制备出来的样品在Li+掺杂浓度较高的情况下仍能保持良好的晶型,随着Li+共掺浓度的增大,Er3+Y2O3纳米晶体在绿光和红光波段的上转换发光强度有了显著的提高。造成发光增强的原因是Li+的引入改变了Er3+Y2O3的晶格对称性,从而提高了Er3+中4f组态内层电子的跃迁几率。
Abstract
The upconversion luminescent properties are investigated in Li+ and Er3+ codoped Y2O3 nanocrystals, especially the effect of the Li+ molar fraction on the crystalline structure and the luminescent intensity. Results indicate that the samples prepared by combustion method have good crystallinity even with high Li+ codoping concentration. The luminescent test results show that with the increase of the Li+ codoping concentration, the upconversion luminescent intensity of the nanocrystals in green and red range will enhance remarkably. The lattice symmetry of the nanocrystals is modified by codoping Li+, which increases the intra-4f transition probability in Er3+.
吕健滔, 王可嘉, 刘劲松, 张清泉, 朱启华, 曾小明, 姚建铨. Li+与Er3+共掺Y2O3纳米晶体上转换发光增强研究[J]. 光学学报, 2011, 31(11): 1116001. Lü Jiantao, Wang Kejia, Liu Jinsong, Zhang Qingquan, Zhu Qihua, Zeng Xiaoming, Yao Jianquan. Enhancement of Upconversion Luminescence in Li+ Codoping Er3+:Y2O3 Nanocrystals[J]. Acta Optica Sinica, 2011, 31(11): 1116001.