红外与毫米波学报, 2012, 31 (1): 21, 网络出版: 2012-02-13  

Nd掺杂对BiFeO3薄膜微结构和电学性能的影响

The effect of Nd doping on microstructure and electrical properties of BiFeO3 thin films
作者单位
1 中国科学院上海技术物理研究所 红外物理国家重点实验室,上海 200083
2 华东师范大学 极化材料与器件教育部重点实验室,上海 200241
摘要
采用化学溶液方法,在LaNiO3/Si(100)衬底上生长了Nd掺杂的BiFeO3薄膜.XRD分析结果表明,随着Nd掺杂量的增加,薄膜晶格变小,Nd掺杂量为20%时,薄膜出现杂相.介电测试表明,随着Nd掺杂量的增加,介电常数和损耗减小,Nd掺杂量为2%的薄膜表现出很强的介电色散现象并出现介电损耗弛豫峰,其符合类德拜模型特征.随着Nd掺杂量增加,薄膜的漏电流减小,在低电场下,电流输运遵从SCLC模型,在高场下,电流输运遵循Poole-Frenkel模型.分析结果表明Nd掺杂对薄膜微结构和电学性能有显著影响.
Abstract
The Nd doped BiFeO3 thin films are prepared on LaNiO3/Si (100) substrate by chemical solution deposition method. The results of x-ray diffraction show that the lattice constant of thin films decreases with the increase of Nd content. The impurity phases are found in the thin film with 20% Nd content. The results of dielectric measurement indicate that the dielectric constant and loss of thin films decrease with the increase of Nd content. A very strong dielectric frequency dispersion and relaxation of dielectric loss peak occurs in the thin film with 2% Nd content and it follows Debye-like law. The leakage current of thin films decreases with the increase of Nd content. The current transport follows SCLC model in low electric field region and follows Poole-Frenkel model in high electric field region. These results suggest that Nd doping has a strong influence on microstructure and electric properties of BiFeO3 thin films.

高成, 杨静, 孟祥建, 白伟, 林铁, 孙璟兰, 褚君浩. Nd掺杂对BiFeO3薄膜微结构和电学性能的影响[J]. 红外与毫米波学报, 2012, 31(1): 21. GAO Chen, YANG Jing, MENG Xiang-Jian, BAI Wei, LIN Tie, SUN Jing-Lan, CHU Jun-Hao. The effect of Nd doping on microstructure and electrical properties of BiFeO3 thin films[J]. Journal of Infrared and Millimeter Waves, 2012, 31(1): 21.

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