光谱学与光谱分析, 2014, 34 (12): 3292, 网络出版: 2014-12-08  

不同表面修饰和尺寸的纳米银的荧光增强效应的研究

Fluorescence Enhancement Effect of Silver Nanoparticles with Different Surface Modifiers and Sizes
作者单位
1 电子科技大学中山学院化学与生物工程学院, 广东 中山528402
2 电子科技大学微电子与固体电子学院, 电子薄膜与集成器件国家重点实验室, 四川 成都610054
3 清华大学新型陶瓷与精细工艺国家重点实验室, 北京100084
摘要
分别以柠檬酸钠(CTS)和聚乙烯吡咯烷酮(PVP)为表面修饰剂, 采用化学法制备纳米银(分别标记为Ag-CTS和Ag-PVP)。 当甲基橙溶液中加入Ag-CTS或Ag-PVP时, S2→S0和S1→S0荧光强度分别明显减弱和增强。 不同的是Ag-PVP引起S2→S0和S1→S0荧光强度减弱和增强的幅度更大, 且S2→S0荧光峰出现红移。 当甲基橙溶液中加入Ag-CTS时, S1→S0荧光强度随时间延长逐渐增强, 而加入Ag-PVP时, S1→S0荧光强度则不随时间而变化。 颗粒尺寸较大的片状结构纳米银引起S1→S0荧光强度增强比率较小。 甲基橙溶液浓度越低, S1→S0荧光强度增强比率越大。 研究结果表明, 纳米银表面吸附的不同表面修饰剂通过影响纳米银与甲基橙分子间距离进而影响纳米银的荧光增强效应;纳米银尺寸大小则由于所产生的局域面表面等离子共振特点等差异影响其局域场增强效应。
Abstract
Silver nanoparticles were prepared by chemical method using citricacid trisodiumsalt (Ag-CTS) and polyvinylpyrrolidone (Ag-PVP) as surface modifiers, respectively. When Ag-CTS or Ag-PVP nanoparticles were added into methyl orange (MO) solution, the enhanced-fluorescence of S1→S0 and quenched-fluorescence of S2→S0 were simultaneously observed. However, for the solution containing Ag-PVP, the red-shift of fluorescence peak of S1→S0 was observed and the extents of the enhanced-fluorescence of S1→S0 and quenched-fluorescence of S2→S0 are higher than those of the solution containing Ag-CTS. With the increase in reaction time the fluorescence intensity of S1→S0 increased gradually in the solution containing Ag-CTS nanoparticles and no change was observed in the solution containing Ag-PVP nanoparticles. The lower the MO concentration, the higher the fluorescence intensity ratio of S1→S0. The results indicated that the silver nanoparticles with different surface modifiers affect the metal-enhanced fluorescence by impacting the distance between the methyl orange and silver nanoparticles. The size of silver nanoparticles affects the metal-enhanced fluorescence due to the difference in the surface plasma resonance properties.

王悦辉, 熊娜娜, 周济. 不同表面修饰和尺寸的纳米银的荧光增强效应的研究[J]. 光谱学与光谱分析, 2014, 34(12): 3292. WANG Yue-hui, XIONG Na-na, ZHOU Ji. Fluorescence Enhancement Effect of Silver Nanoparticles with Different Surface Modifiers and Sizes[J]. Spectroscopy and Spectral Analysis, 2014, 34(12): 3292.

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