光学学报, 2015, 35 (2): 0230002, 网络出版: 2015-01-20  

X射线束斑强度分布对EDXRF分析精度影响研究

Study on Influence of X-Ray Beam Spot Intensity on EDXRF Analytical Precision
作者单位
长春理工大学理学院, 吉林 长春 130022
摘要
能量色散X射线荧光(EDXRF)光谱法分析复杂背景样品中的低含量元素时,X 射线散射产生的干扰会影响系统检测精度,而X 射线散射与X 射线束斑强度密切相关。利用微光像增强器采集了不同工作电流下X 射线束斑的投影图像,用投影光斑外围杂散射线强度表征X 射线散射强度,分析得到了减小X 射线束斑强度的两种方式,即降低X 射线管工作电流和减小准直器孔径。通过实验对比发现,利用EDXRF 法分析样品中低组分元素时,用减小准直器孔径的方法来降低X 射线散射,要比降低X 射线管电流的方式更加有效,且减小准直器孔径的同时增大X 射线管工作电流能够提高系统检测精度。实验结果表明,该方法检测土壤中微量元素Cr 时,实际相对误差为0.9%~6.6%,相对标准偏差为0.7%~1.5%,经过t 检验,p>0.05,测试结果在统计学上与标准样品结果无显著差异。
Abstract
When energy dispersive X-ray fluorescence (EDXRF) spectroscopy is used to analyze low-content element in samples with complicated background, interference from X-ray scattering will affect system detection precision, and X-ray scattering is closely related to X-ray beam spot intensity. A shimmer image intensifier is utilized to collect projection image of X-ray beam spot under different working current and the intensity of mixed and scattered ray around the projection flare is used to characterize X-ray scattering intensity, two methods to reduce X-ray beam spot intensity, i.e. reducing X-ray tube current and collimator diameter, are obtained so as to reduce the impact of the mixed and scattered ray on X-ray. It is found that when the EDXRF method is used to analyze low-content element in samples, the method of reducing collimator diameter is more effective than the method of reducing X-ray tube current for decrease of X-ray scattering, and the system detection precision can be improved when the collimator diameter is reduced and the X-ray tube current is increased meanwhile. The experimental results show that for detecting microelement Cr in the soil, actual relative error of this method is 0.9%~6.6%, and relative standard deviation is 0.7%~1.5%. p is higher than 0.05 in t test, and the test result has no significant difference with standard samples statistically.

秦旭磊, 端木庆铎, 宋忠华, 李野, 李珅, 刘有银, 王国政. X射线束斑强度分布对EDXRF分析精度影响研究[J]. 光学学报, 2015, 35(2): 0230002. Qin Xulei, Duanmu Qingduo, Song Zhonghua, Li Ye, Li Shen, Liu Youyin, Wang Guozheng. Study on Influence of X-Ray Beam Spot Intensity on EDXRF Analytical Precision[J]. Acta Optica Sinica, 2015, 35(2): 0230002.

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