红外技术, 2016, 38 (9): 788, 网络出版: 2016-10-19  

耐温型 1.06 μm近红外吸收涂层的制备及性能表征

Preparation and Property Characterization of Heat-resistant 1.06 μm Near-infrared Absorption Composite Coatings
作者单位
1 滁州学院材料与化学工程学院,安徽滁州 239000
2 南京航空航天大学材料科学与技术学院,江苏南京 211106
摘要
以 Sm2O3为颜料,环氧改性有机硅为粘合剂,采用喷涂法制备了环氧改性有机硅/Sm2O3复合涂层。系统研究了热处理温度及热处理时间对所制备涂层微结构、近红外吸收性能及力学性能的影响。结果表明:环氧改性有机硅 /Sm2O3复合涂层最高可耐受温度可达到 300℃,在 300℃下热处理 5h后,涂层微结构保持不变,对 1.06 .m近红外光的反射率可低至 47.7%,涂层的硬度可达到 4H,附着力 2级,耐冲击强度 40 kg.cm。所制备涂层在 250℃下可长时间使用,在 250℃下热处理 100 h后,涂层微结构仍然保持不变,对 1.06 .m近红外光的反射率可低至 49.7%,涂层的硬度、附着力和耐冲击强度可分别保持在 4 H、2级和 40 kg.cm。
Abstract
Epoxy-modified silicone/Sm2O3 composite coatings were prepared by using Sm2O3 powders and epoxy-modified silicone as pigments and adhesives, respectively. The effect of heat treatment temperature and heat treatment time on the microstructure, near-infrared absorption properties, and mechanical properties of the as-prepared coatings were systematically studied. The results indicate that the maximum withstand temperature of epoxy-modified silicone/Sm2O3 composite coatings can reach 300℃. After heat treatment at 300℃ with 5 h, the microstructure of the coatings remain unchanged, the near-infrared reflectivity at 1.06μm can be as low as 47.7%, and the hardness, adhesion strength, and impact strength of the coatings can reach 4H, 2 grade, and 40 kg.cm, respectively. The prepared coatings can be used long-term at 250℃, after heat treatment at 250℃ with 100 h, the microstructure of the coatings remain unchanged, the near-infrared reflectivity at 1.06.m can be as low as 49.7%, the hardness, adhesion strength, and impact strength of the coatings can be maintained at 4H, 2 grade, and 40 kg.cm, respectively.

张伟钢, 黄萍, 薛连海, 陈玉萍, 徐国跃. 耐温型 1.06 μm近红外吸收涂层的制备及性能表征[J]. 红外技术, 2016, 38(9): 788. ZHANG Weigang, HUANG Ping, XUE Lianhai, CHEN Yuping, XU Guoyue. Preparation and Property Characterization of Heat-resistant 1.06 μm Near-infrared Absorption Composite Coatings[J]. Infrared Technology, 2016, 38(9): 788.

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