中国激光, 2019, 46 (2): 0211001, 网络出版: 2019-05-09
西林瓶内氧气含量在线检测的基线快速校正方法 下载: 931次
Fast Baseline Correction Method for Online Detection of Oxygen Content in Vials
光谱学 基线校正 Levenberg-Marquardt算法 氧气含量 波长调制光谱 spectroscopy baseline correction Levenberg-Marquardt algorithm oxygen content wavelength modulation spectroscopy
摘要
构建了一个开放单光路短光程激光检测平台,提出了一种基于线型的Levenberg-Marquardt(L-M)算法,以洛伦兹线型和高斯线型的二阶导数作为L-M算法的拟合函数,对氧气体积分数为0%~21%的样本进行校正。结果表明:在基于洛伦兹线型的L-M算法校正中,氧气含量-二次谐波峰值的拟合系数最高,为0.9995;以洛伦兹线型为优化依据,对含氧气体积分数为1%的样品进行了多次测量,校正处理前后预测的氧气体积分数最大偏差分别为0.38%和0.22%,预测的均方根误差分别为0.25%和0.16%。
Abstract
A laser detection platform with an open single path and short optical distance is constructed, and a Levenberg-Marquardt (L-M) algorithm based on linetype is proposed. The method uses second order derivative of Gaussian linetype and Lorenz linetype as the fitting function of L-M algorithm. The samples with oxygen volume fraction of 0%-21% are corrected. The results show that the correlation coefficients of oxygen content and peak is the highest in L-M algorithm correction based on Lorentz linetype (0.9995). The sample with oxygen volume fraction of 1% is measured several times on the basis of Lorentz linetype. Compared with the measured results before and after the correction, the predicted maximum deviations of oxygen volume fraction are 0.38% and 0.22%, respectively, and the root mean square errors of prediction are 0.25% and 0.16%, respectively.
朱高峰, 朱红求, 钱灏, 朱剑平. 西林瓶内氧气含量在线检测的基线快速校正方法[J]. 中国激光, 2019, 46(2): 0211001. Gaofeng Zhu, Hongqiu Zhu, Hao Qian, Jianping Zhu. Fast Baseline Correction Method for Online Detection of Oxygen Content in Vials[J]. Chinese Journal of Lasers, 2019, 46(2): 0211001.