Photonics Research, 2019, 7 (5): 05000494, Published Online: Apr. 12, 2019  

Revealing of the ultrafast third-order nonlinear optical response and enabled photonic application in two-dimensional tin sulfide Download: 790次

Author Affiliations
1 Shenzhen Engineering Laboratory of Phosphorene and Optoelectronics, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China
2 Faculty of Information Technology, Macau University of Science and Technology, Macao, China
3 College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China
4 School of Materials Science and Energy Engineering, Foshan University, Foshan 528000, China
5 e-mail: jiangxtemail@sina.com
6 e-mail: chenhongcs@126.com
Abstract
Black phosphorus (BP), a typical mono-elemental and two-dimensional (2D) material, has gathered significant attention owing to its distinct optoelectronic properties and promising applications, despite its main obstacle of long-term stability. Consequently, BP-analog materials with long-term chemical stability show additional potential. In this contribution, tin sulfide (SnS), a novel two-elemental and 2D structural BP-analog monochalcogenide, has been demonstrated to show enhanced stability under ambient conditions. The broadband nonlinear optical properties and carrier dynamics have been systematically investigated via Z-scan and transient absorption approaches. The excellent nonlinear absorption coefficient of 50.5×10 3 cm/GW, 1 order of magnitude larger than that of BP, endows the promising application of SnS in ultrafast laser generation. Two different decay times of τ1873 fs and τ296.9 ps allow the alteration between pure Q switching and continuous-wave (CW) mode locking in an identical laser resonator. Both mode-locked and Q-switched operations have been experimentally demonstrated using an SnS saturable absorber at the telecommunication window. Femtosecond laser pulses with tunable wavelength and high stability are easily obtained, suggesting the promising potential of SnS as an efficient optical modulator for ultrafast photonics. This primary investigation may be considered an important step towards stable and high-performance BP-analog material-based photonic devices.

Zhongjian Xie, Feng Zhang, Zhiming Liang, Taojian Fan, Zhongjun Li, Xiantao Jiang, Hong Chen, Jianqing Li, Han Zhang. Revealing of the ultrafast third-order nonlinear optical response and enabled photonic application in two-dimensional tin sulfide[J]. Photonics Research, 2019, 7(5): 05000494.

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