首页 > 论文 > 中国激光 > 46卷 > 7期(pp:711002--1)

基底辅助激光诱导击穿光谱技术检测润滑油中的金属元素

Detection of Metallic Elements in Lubricating Oil by Substrate-Assisted Laser-Induced Breakdown Spectroscopy

  • 摘要
  • 论文信息
  • 参考文献
  • 被引情况
  • PDF全文
分享:

摘要

采用基底辅助激光诱导击穿光谱技术,以标准油中的Mg、Ti、Ni与Cr为目标元素进行定量分析。选定Mg II 279.55 nm、Ti I 334.94 nm、Ni I 352.45 nm与Cr I 425.44 nm为目标元素的定量分析谱线进行分析。考察样品预处理静置时间、样品油膜平均厚度、探测延时和激光脉冲能量对Mg、Ti、Ni与Cr元素光谱信号强度与信背比的影响。在最优的实验条件下,利用6个标准油样品建立了标准曲线定标模型,得出Mg、Ti、Ni与Cr的检出限分别为3.10,8.17,18.79,6.10 μg·g -1。基于定标曲线,预测了另外5个标准油样品中Mg、Ti、Ni与Cr的质量比,相对误差分别为7.43%、8.91%、13.66%与10.40%。

Abstract

Quantitative analysis of target elements Mg, Ti, Ni, and Cr in standard oil was performed using substrate-assisted laser-induced breakdown spectroscopy. Mg II 279.55 nm, Ti I 334.94 nm, Ni I 352.45 nm, and Cr I 425.44 nm were selected as the spectral lines of the target elements in the quantitative analysis. The effects of sample pretreatment time, average sample oil film thickness, detection delay, and energy of laser pulse on the spectral signal intensity and signal-to-background ratio of Mg, Ti, Ni, and Cr were investigated. Under the optimal experimental conditions, the standard curve calibration model was established using six standard oil samples. The limits of detection of Mg, Ti, Ni, and Cr were 3.10, 8.17, 18.79, and 6.10 μg·g -1, respectively. The mass ratios of Mg, Ti, Ni, and Cr in other five standard oil samples were predicted by the calibration curve, and the relative errors were 7.43%, 8.91%, 13.66%, and 10.40%, respectively.

Newport宣传-MKS新实验室计划
补充资料

DOI:10.3788/CJL201946.0711002

所属栏目:光谱学

基金项目:国家自然科学基金、重庆市留学人员回国创业创新支持计划、重庆市留学人员回国创业创新支持计划、重庆市基础科学与前沿技术研究专项项目一般项目;

收稿日期:2019-03-04

修改稿日期:2019-03-28

网络出版日期:2019-07-01

作者单位    点击查看

郑培超:重庆邮电大学光电工程学院, 光电信息感测与传输技术重庆市重点实验室, 重庆 400065
谭癸宁:重庆邮电大学光电工程学院, 光电信息感测与传输技术重庆市重点实验室, 重庆 400065
王金梅:重庆邮电大学光电工程学院, 光电信息感测与传输技术重庆市重点实验室, 重庆 400065
赵怀冬:重庆邮电大学光电工程学院, 光电信息感测与传输技术重庆市重点实验室, 重庆 400065
刘冉宁:重庆邮电大学光电工程学院, 光电信息感测与传输技术重庆市重点实验室, 重庆 400065

联系人作者:郑培超, 王金梅(wangjm@cqupt.edu.cn, wangjm@cqupt.edu.cn)

备注:国家自然科学基金、重庆市留学人员回国创业创新支持计划、重庆市留学人员回国创业创新支持计划、重庆市基础科学与前沿技术研究专项项目一般项目;

【1】Liu L M, Xu H F, Xiao J K et al. Effect of heat treatment on structure and property evolutions of atmospheric plasma sprayed NiCrBSi coatings. Surface and Coatings Technology. 325, 548-554(2017).

【2】Liu L M, Xiao J K, Wei X L et al. Effects of temperature and atmosphere on microstructure and tribological properties of plasma sprayed FeCrBSi coatings. Journal of Alloys and Compounds. 753, 586-594(2018).

【3】Johansson S, Frennfelt C, Killinger A et al. Frictional evaluation of thermally sprayed coatings applied on the cylinder liner of a heavy duty diesel engine: pilot tribometer analysis and full scale engine test. Wear. 273(1), 82-92(2011).

【4】Fu X S, Yao W Z, Zhang L H et al. The current status and development trend of additives in lubricating oils Automobile Technology & Material. 2005(5), 1-6(0).
伏喜胜, 姚文钊, 张龙华 等. 润滑油添加剂的现状及发展趋势 汽车工艺与材料. 2005(5), 1-6(0).

【5】Li S, Qin H J, Zuo R F et al. Tribological performance of Mg/Al/Ce layered double hydroxides nanoparticles and intercalated products as lubricant additives. Applied Surface Science. 353, 643-650(2015).

【6】Li S, Qin H J, Zuo R F et al. Friction properties of La-doped Mg/Al layered double hydroxide and intercalated product as lubricant additives. Tribology International. 91, 60-66(2015).

【7】Aucélio R Q, de Souza R M, de Campos R C et al. . The determination of trace metals in lubricating oils by atomic spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy. 62(9), 952-961(2007).

【8】Zmozinski A V, de Jesus A, Vale M G R et al. . Determination of calcium, magnesium and zinc in lubricating oils by flame atomic absorption spectrometry using a three-component solution. Talanta. 83(2), 637-643(2010).

【9】Zali M A. Ahmad W K W, Retnam A, et al. Concentration of heavy metals in virgin, used, recovered and waste oil: a spectroscopic study. Procedia Environmental Sciences. 30, 201-204(2015).

【10】Duyck C and Miekeley N. Portoda Silveira C L, et al. Trace element determination in crude oil and its fractions by inductively coupled plasma mass spectrometry using ultrasonic nebulization of toluene solutions. Spectrochimica Acta Part B: Atomic Spectroscopy. 57(12), 1979-1990(2002).

【11】He Y M, Zhao F F, Zhou Y et al. Extraction induced by emulsion breaking as a tool for simultaneous multi-element determination in used lubricating oils by ICP-MS. Analytical Methods. 7(11), 4493-4501(2015).

【12】Mello P A. Pereira J S F, Mesko M F, et al. Sample preparation methods for subsequent determination of metals and non-metals in crude oil: a review. Analytica Chimica Acta. 746, 15-36(2012).

【13】Zheng P C, Liu H D, Wang J M et al. Online mercury determination by laser-induced breakdown spectroscopy with the assistance of solution cathode glow discharge. Journal of Analytical Atomic Spectrometry. 30(4), 867-874(2015).

【14】Wang J M, Zheng P C, Liu H D et al. Classification of Chinese tea leaves using laser-induced breakdown spectroscopy combined with the discriminant analysis method. Analytical Methods. 8(15), 3204-3209(2016).

【15】Guo Y M, Deng L M, Yang X Y et al. Wavelet-based interference correction for laser-induced breakdown spectroscopy. Journal of Analytical Atomic Spectrometry. 32(12), 2401-2406(2017).

【16】Zhu Z H, Li J M, Guo Y M et al. Accuracy improvement of boron by molecular emission with a genetic algorithm and partial least squares regression model in laser-induced breakdown spectroscopy. Journal of Analytical Atomic Spectrometry. 33(2), 205-209(2018).

【17】Jia J W, Fu H B, Wang H D et al. Improvement of beam shape modification on stability of laser induced breakdown spectroscopy. Chinese Journal of Lasers. 46(3), (2019).
贾军伟, 付洪波, 王华东 等. 光束整形对激光诱导击穿光谱稳定性的改善. 中国激光. 46(3), (2019).

【18】Fichet P, Mauchien P, Wagner J F et al. Quantitative elemental determination in water and oil by laser induced breakdown spectroscopy. Analytica Chimica Acta. 429(2), 269-278(2001).

【19】Yaroshchyk P. Morrison R J S, Body D, et al. Quantitative determination of wear metals in engine oils using laser-induced breakdown spectroscopy: a comparison between liquid jets and static liquids. Spectrochimica Acta Part B: Atomic Spectroscopy. 60(7/8), 986-992(2005).

【20】Xiu J S, Bai X S, Motto-Ros V et al. Characteristics of indirect laser-induced plasma from a thin film of oil on a metallic substrate. Frontiers of Physics. 10(2), 231-239(2015).

【21】Xiu J S, Liu Y Y, Dong L L et al. The detection of trace wear elements in engine oil using indirect ablation-laser induced breakdown spectroscopy. Spectroscopy and Spectral Analysis. 37(9), 2885-2890(2017).
修俊山, 刘云燕, 董丽丽 等. 机油中痕量磨损金属元素的间接烧蚀LIBS探测研究. 光谱学与光谱分析. 37(9), 2885-2890(2017).

【22】Wang J M, Xue S W, Zheng P C et al. Determination of lead and copper in ligusticum wallichii by laser-induced breakdown spectroscopy. Analytical Letters. 50(12), 2000-2011(2017).

【23】Wang J, Shi M, Zheng P et al. Quantitative analysis of Ca, Mg, and K in the roots of angelica pubescens f. biserrata by laser-induced breakdown spectroscopy combined with artificial neural networks. Journal of Applied Spectroscopy. 85(1), 190-196(2018).

【24】Wang J M, Yan H Y, Zheng P C et al. Quantitative detection of nutrient elements in soil based on laser induced breakdown spectroscopy. Chinese Journal of Lasers. 44(11), (2017).
王金梅, 颜海英, 郑培超 等. 基于激光诱导击穿光谱定量检测土壤中营养元素的研究. 中国激光. 44(11), (2017).

引用该论文

Peichao Zheng, Guining Tan, Jinmei Wang, Huaidong Zhao, Ranning Liu. Detection of Metallic Elements in Lubricating Oil by Substrate-Assisted Laser-Induced Breakdown Spectroscopy[J]. Chinese Journal of Lasers, 2019, 46(7): 0711002

郑培超, 谭癸宁, 王金梅, 赵怀冬, 刘冉宁. 基底辅助激光诱导击穿光谱技术检测润滑油中的金属元素[J]. 中国激光, 2019, 46(7): 0711002

您的浏览器不支持PDF插件,请使用最新的(Chrome/Fire Fox等)浏览器.或者您还可以点击此处下载该论文PDF