原子与分子物理学报, 2005, 22 (3): 568, 网络出版: 2006-06-11
激光偏振特性对丙酮和氧气多光子电离质谱信号的影响
Different influences of laser polarization on REMPI mass spectroscopy of oxygen and acetone molecules
摘要
在极性分子丙酮复合物CH3COCH3*H2O和非极性分子氧气的REMPI谱中,母体离子信号强度与激光偏振方向的关系是不同的.改变532 nm激光偏振方向,记录了两种分子母体离子信号强度,实验结果表明,对于氧气分子的母体离子信号强度,激光偏振方向的改变对其没有影响,而对于CH3COCH3*H2O的母体离子信号强度,随偶极矩与激光偏振方向夹角的增加,其母体离子信号强度呈余弦曲线变化,且与夹角余弦的2.1次幂成正比.理论分析显示,CH3COCH3*H2O的REMPI母体离子信号强度应与此夹角的余弦的2次幂成正比.这就说明实验结果和理论分析是相符的.
Abstract
The REMPI mass spectroscopy of O_2 and CH_3COCH _3 ·H_2O displayed that the dependence of their mother ion signal intensity to la ser polarization direction is different. In the course of our experiment, chang e the polarization direction of 532 nm laser and recorder their mother ion signal intensity. The results show that the changes of laser polariz a tion have no influence to mother ion signal intensity of non-polar molecule O_ 2. And for polar molecule CH_3COCH_3·H_2O, its mother ion signal intensity c hanges with the changes of laser polarization. With the angle α of molecul ar dipo le moment to laser polarization increasing from 0° to 90°, the mother ion sig nal intensity decreases in according to cosine curve of angle α, and is in direct proportion to coa 2.1 α.Theory analysis show that mother ion intensity of CH_3COCH_3·H_2O is direct proportion to co 2.1 α. T his indicates that experimental results is well consistent with theory analysis.
张霞, 孔祥和, 樊新岩, 张树东, 王仍, 蔡廷栋. 激光偏振特性对丙酮和氧气多光子电离质谱信号的影响[J]. 原子与分子物理学报, 2005, 22(3): 568. 张霞, 孔祥和, 樊新岩, 张树东, 王仍, 蔡廷栋. Different influences of laser polarization on REMPI mass spectroscopy of oxygen and acetone molecules[J]. Journal of Atomic and Molecular Physics, 2005, 22(3): 568.