激光与光电子学进展, 2017, 54 (1): 013101, 网络出版: 2017-01-17   

脉冲激光沉积法合成(Bi,Er)2Ti2O7介电薄膜及其上转换发光 下载: 668次

Synthesization of (Bi,Er)2Ti2O7 Dielectric Thin Films by Pulse Laser Deposition Method and Its Up-Conversion Luminescence
作者单位
中山大学新华学院信息科学系, 广东 广州 510520
摘要
采用脉冲激光沉积法在透明导电(ITO)玻璃衬底上制备(Bi, Er)2Ti2O7介电薄膜。当沉积温度范围控制在500~600 ℃时, 均可获得纯度较高的Bi2Ti2O7薄膜。常温下, Bi2Ti2O7薄膜的介电常数的范围为166~178, 随频率和温度变化比较稳定, 介电损耗低于0.05。通过分析光谱, 发现薄膜的上转换光谱包含发光中心为527 nm和548 nm的绿光带及发光中心为660 nm的红光带, 分别对应Er3+离子从发射能级2H11/2、4S3/2和4F9/2向基态能级4I15/2的跃迁。(Bi, Er)2Ti2O7薄膜是一种多功能材料, 有望在透明光电器件中得到广泛应用。
Abstract
(Bi,Er)2Ti2O7 dielectric thin films are synthesized on indium-tin-oxide (ITO) glass substrates by the pulse laser deposition method. The pure Bi2Ti2O7 thin films can be obtained when the deposition temperature is controlled in the range of 500~600 ℃. The range of dielectric constant of (Bi,Er)2Ti2O7 thin film is 166~178 and the dielectric loss is less than 0.05 at room temperature. When the frequency and the temperature are changing, the dielectric constant remains stable. The spectral analysis shows that the up-conversion luminescence spectra of thin films contain two green light emission bands centered at 527 nm and 548 nm and a red light emission band centered at 660 nm. These emission bands correspond to the transition of Er3+ from 2H11/2, 4S3/2 and 4F9/2 levels to the ground level 4I15/2. (Bi,Er)2Ti2O7 thin films can be considered as a kind of multifunctional material, which will be widely applied to transparent optoelectronic devices in the future.

梁立容, 王凤, 邱泽敏. 脉冲激光沉积法合成(Bi,Er)2Ti2O7介电薄膜及其上转换发光[J]. 激光与光电子学进展, 2017, 54(1): 013101. Liang Lirong, Wang Feng, Qiu Zemin. Synthesization of (Bi,Er)2Ti2O7 Dielectric Thin Films by Pulse Laser Deposition Method and Its Up-Conversion Luminescence[J]. Laser & Optoelectronics Progress, 2017, 54(1): 013101.

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