发光学报, 2017, 38 (2): 207, 网络出版: 2017-02-09  

基于PVP和PbSe 三维自组装超晶格复合体系的电双稳器件

Electrical Bistable Devices Based on Composites of Polyvinyl Pyrrolidone and Three Dimensional Self-assembled Lead Selenide Superlattices
作者单位
1 北京交通大学 发光与光信息教育部重点实验室, 北京 100044
2 苏州瑞晟太阳能有限公司, 江苏 苏州 215123
摘要
采用旋涂工艺将PbSe三维自组装超晶格镶嵌在两层聚合物PVP中,制备了基于PVP和PbSe三维自组装超晶格复合体系的电双稳器件,器件结构为ITO/PVP/PbSe 三维自组装超晶格/PVP/Al,研究了其电学性能和记忆效应。与参比器件ITO/PVP/Al相比,器件ITO/PVP/PbSe三维自组装超晶格/PVP/Al的电流-电压特性呈现出非常明显的电双稳特性和非易失记忆行为,在相同的电压下同时具有两种不同的导电状态:低电导的关态和高电导的开态。当PVP与PbSe超晶格的质量比为1∶1时,器件性能最好,其最大电流开关比为7×104,经过104 s仍几乎无衰减。通过对电流-电压曲线拟合,利用不同的导电模型对器件的载流子传输机制进行了解释。结果表明,PbSe三维自组装超晶格作为电荷陷阱,可以俘获、储存及释放电荷,对器件的电双稳性能能起决定性作用。
Abstract
Electrical bistable devices utilizing three dimensional self-assembled lead selenide (PbSe) superlattices embedded between two polyvinyl pyrrolidone (PVP) layers were fabricated by using spin-coating technique. Each PbSe superlattice is a cluster with a uniform size of 50-60 nm, which consists of hundreds of PbSe nanoparticles with an average size of 5 nm. The current-voltage characteristics for the devices with an architecture of indium-tin-oxide (ITO)/PVP/PbSe superlattices/PVP/Al exhibit electrical bistabilities and memory behaviors due to the trapping, storring, and detrapping of the PbSe superlattices. The maximum ON/OFF ratio of the current bistability for the optimal device is 7×104, and it is maintained for 1×104 s with little degradation. The electrical bistable properties and the carrier transport mechanisms of the devices are interpreted by the conduction models based on the results of fitting the current-voltage curves.

张振, 钱磊, 韩长峰, 滕枫. 基于PVP和PbSe 三维自组装超晶格复合体系的电双稳器件[J]. 发光学报, 2017, 38(2): 207. ZHANG Zhen, QIAN Lei, HAN Chang-feng, TENG Feng. Electrical Bistable Devices Based on Composites of Polyvinyl Pyrrolidone and Three Dimensional Self-assembled Lead Selenide Superlattices[J]. Chinese Journal of Luminescence, 2017, 38(2): 207.

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