红外与毫米波学报, 2017, 36 (5): 606, 网络出版: 2017-11-21  

基于二维相关分析的ZnS材料声子交互作用

Multi-phonon interaction of ZnS material based on two-dimensional correlation analysis
作者单位
1 中国航天科工飞航技术研究院 天津津航技术物理研究所, 天津市薄膜光学重点实验室, 天津, 300308
2 哈尔滨工业大学 光电子技术研究所, 可调谐激光技术国防科技重点实验室, 黑龙江 哈尔滨, 150080
摘要
硫化锌材料是长波红外光学窗口材料优选材料之一.针对化学气相沉积(CVD)和热压成形(HP)两种工艺制备的硫化锌材料, 研究了从室温到600℃的光谱透过率变化现象, 基于二维相关光谱分析技术, 获得了长波吸收区内的声子交互作用.研究结果表明: 在700~1250 cm-1的长波吸收波段, CVD ZnS的声子频率为横向振动模式下(TO)的三次谐波频率和纵向声学模式下(LA)的三次谐波频率;HP ZnS的声子频率分别为3TO、3LA和4LA, 并且在温度作用下的响应顺序依次为3LA、3TO和4LA.两种工艺制备的ZnS杂质振动吸收在温度作用下对2000~1250 cm-1范围内的光谱透过率产生影响, 出现不同程度的透过率增加现象, 由于两者含有杂质的区别, 在高温下CVD ZnS的透过率变化比HP ZnS较为显著.
Abstract
Zinc sulfide material is one of the important materials for infrared optical window in the long wavelength region. In this paper, the change of the spectral transmittance from room temperature to 600℃ was studied for the zinc sulfide materials prepared by chemical vapor deposition (CVD) and hot pressing (HP). Based on the two-dimensional correlation spectrum analysis technique, the interaction of the phonons in the long wave absorption region was obtained. In the long wave absorption band from 700 cm-1 to 1 250 cm-1, the phonon frequencies of CVD ZnS is the third harmonic frequencies in the transverse vibration mode (TO) and the third harmonic frequency in the longitudinal acoustic mode (LA). The phonon frequencies of HP ZnS are 3TO, 3LA and 4LA, and the response under temperature is 3LA, 3TO and 4LA in proper order. The vibration absorption of ZnS impurity prepared by the two techniques has an effect on the spectral transmittance in the range from 1250 cm-1 to 2000 cm-1 under the action of temperature, and the increase of the transmittance in different degrees occurs. Because of the difference of impurities, the transmittance of CVD ZnS is more significant than that of HP ZnS at high temperature environment.

刘华松, 杨霄, 刘丹丹, 李士达, 季一勤, 张锋, 陈德应. 基于二维相关分析的ZnS材料声子交互作用[J]. 红外与毫米波学报, 2017, 36(5): 606. LIU Hua-Song, YANG Xiao, LIU Dan-Dan, LI Shi-Da, JI Yi-Qin, ZHANG Feng, Chen De-Ying. Multi-phonon interaction of ZnS material based on two-dimensional correlation analysis[J]. Journal of Infrared and Millimeter Waves, 2017, 36(5): 606.

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!