发光学报, 2019, 40 (7): 849, 网络出版: 2019-07-31  

铕离子掺杂七铝酸十二钙蓝光发射导电荧光粉的制备及其光学特性

Preparation and Optical Properties of Eu2+ Doped 12CaO·7Al2O3 Blue Emitting Conductive Phosphors
作者单位
东北师范大学 物理学院, 吉林 长春 130024
摘要
采用碳包埋方法制备了不同Eu2+掺杂浓度的七铝酸十二钙(C12A7∶x%Eu2+)导电荧光粉。在254 nm的紫外光激发下, 样品呈现出位于444 nm的蓝光宽带发射峰, 其来源于Eu2+的4f65d1-4f7跃迁。当Eu2+的掺杂浓度为1.0%时, 蓝光发射强度最大。通过漫反射吸收光谱结合经验公式可计算C12A7∶1.0%Eu2+粉末样品的困陷于笼中的电子浓度为3.40×1019 cm-3。在空气气氛下对C12A7∶1.0%Eu2+样品进行热处理, 通过减少困陷于笼中的电子浓度, 即增加困陷于笼中的O2-离子浓度, 可进一步提高样品的发光强度。阴极射线发光实验结果表明:铕掺杂七铝酸十二钙蓝光发射导电荧光粉在低压场发射显示器件中有潜在的应用前景。
Abstract
Eu2+ doped 12CaO·7Al2O3 (C12A7∶x% Eu2+) conductive phosphors with different concentrations were synthesized by a melting solidification method. Upon 254 nm UV excitation, we can observe a broad blue emitting band peaked at 444 nm, which originates from the 4f65d1-4f7 transition of Eu2+. As the Eu2+ doping concentration is 1.0%, the strongest emission intensity can be achieved. The conductive performance of Eu2+ doped 12CaO·7Al2O3 phosphors can be attributed to the generation of encaged electrons and the calculated encaged electron concentration is ~3.40×1019 cm-3. After the conductive phosphor was annealed in air, its photoluminescence intensity increased with increasing the amount of encaged O2- anions (i.e. decreasing the amount of encaged electrons). Our results suggest that C12A7∶Eu2+ blue emitting conductive phosphors have a potential application in field emission displays.

高旭, 杨健, 张猛, 刘春光, 祝汉成, 严端廷, 徐长山, 刘玉学. 铕离子掺杂七铝酸十二钙蓝光发射导电荧光粉的制备及其光学特性[J]. 发光学报, 2019, 40(7): 849. GAO Xu, YANG Jian, ZHANG Meng, LIU Chun-guang, ZHU Han-cheng, YAN Duan-ting, XU Chang-shan, LIU Yu-xue. Preparation and Optical Properties of Eu2+ Doped 12CaO·7Al2O3 Blue Emitting Conductive Phosphors[J]. Chinese Journal of Luminescence, 2019, 40(7): 849.

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