首页 > 论文 > 光子学报 > 48卷 > 10期(pp:1031001--1)

WO3/Ag复合薄膜的制备及其电致变色性能

Preparation and Electrochromic Properties of WO3/Ag Composite Film

  • 摘要
  • 论文信息
  • 参考文献
  • 被引情况
  • PDF全文
分享:

摘要

通过水热法在导电玻璃上合成WO3纳米块,利用电沉积技术在WO3纳米块上负载不同含量(20 s、50 s、80 s)的Ag纳米粒子,成功制备出WO3/Ag复合薄膜.通过X射线衍射分析、扫描电子显微镜与能谱对WO3/Ag复合薄膜进行表征,利用电化学测试与光谱测试,得到电致变色可逆性、响应时间、着色效率和光谱透过率等参数,并对其电致变色性能进行分析.结果表明,对比单一WO3纳米块薄膜的电致变色性能,WO3/Ag复合薄膜的电致变色性能显著增强.同时研究了不同Ag纳米粒子含量对WO3/Ag复合薄膜电致变色性能的影响,研究表明沉积50 s的WO3/Ag复合薄膜具有最优异的电致变色性能.

Abstract

WO3 nanoblocks were prepared by hydrothermal method on FTO glass, and WO3/Ag composite film was prepared by electrodepositing different content (20 s, 50 s, 80 s) of Ag nanoparticles onto WO3 nanoblocks. Characterization of WO3/Ag composite films was confirmed by X-ray diffraction analysis, scanning electron microscopy and energy spectroscopy. The parameters of electrochromic reversibility, response time, coloration efficiency and spectral transmittance were obtained by electrochomical measurement technologies and spectral tests. Then, the electrochromic properties were analyzed. The WO3/Ag composite films show the higher electrochromic properties compared with the WO3 nanoblock film. The effects of different Ag nanoparticle content on the electrochromic properties of WO3/Ag composite films were also studied. The results show that the WO3/Ag composite film deposited for 50 s has the best electrochromic properties.

Newport宣传-MKS新实验室计划
补充资料

中图分类号:O646;O614

DOI:10.3788/gzxb20194810.1031001

基金项目:国家自然科学基金(Nos.51502023,11874091),吉林省科技厅研发项目(Nos.20180201033GX,20160520114JH),吉林省教育厅(Nos.20160358,JJKH20181103KJ)

收稿日期:2019-04-08

修改稿日期:2019-08-14

网络出版日期:--

作者单位    点击查看

苗壮:微光夜视技术重点实验室, 西安 710065
杨雪:长春理工大学 理学院, 长春 130022
杨继凯:微光夜视技术重点实验室, 西安 710065长春理工大学 理学院, 长春 130022
侯志鹏:微光夜视技术重点实验室, 西安 710065
张宇飞:长春理工大学 理学院, 长春 130022
王新:长春理工大学 理学院, 长春 130022
王国政:长春理工大学 理学院, 长春 130022

联系人作者:苗壮(15701573@qq.com)

备注:苗壮(1981-),女,高级工程师,硕士,主要研究方向为电子信息工程.

【1】CHEN Jie, ZHU Zhen-cai, WANG Ru-li, et al. Study on electrochromic properties of WO3 thin films[J]. Acta Optica Sinica, 1996, 16(10): 1475-1478.
陈杰, 朱振才, 王汝笠, 等. WO3薄膜的电致变色特性研究[J]. 光学学报, 1996, 16(10): 1475-1478.

【2】WU Ming-xiao, TAIN Jin-peng, TU Cheng-wei, et al. Performance improvement of rubrene/C70 based organic solar cells with WO3 as buffer layer[J]. Journal of Optoelectronics·Laser, 2015, 26(1): 63-67.
吴明晓, 田金鹏, 涂程威, 等. WO3对Rubrene/C70有机太阳能电池性能的改善[J]. 光电子·激光, 2015, 26(1): 63-67.

【3】ZHAO W, WANG X F, ZHENG E, et al. High capacity WO3 film as efficient charge collection electrode for solar rechargeable batteries[J]. Journal of Power Sources, 2017, 350: 28-34.

【4】YANG C, CHEN J F, ZENG X, et al. Design of the alkali-metal-doped WO3 as a near-infrared shielding material for smart window[J]. Industrial & Engineering Chemistry Research, 2014, 53(46): 17981-17988.

【5】LEE S H , DESHPANDE R , PARILLA P A, et al. Crystalline WO3 nanoparticles for highly improved electrochromic applications[J]. Advanced Materials, 2010, 18(6):763-766.

【6】HUANG B R, LIN T C, LIU Y M. WO3/TiO2 core-shell nanostructure for high performance energy-saving smart windows[J]. Solar Energy Materials and Solar Cells, 2015, 133: 32-38.

【7】DELEON J M O R, ACOSTA D R, PAL U, et al. Improving electrochromic behavior of spray pyrolised WO3 thin solid films by Mo doping[J]. Electrochimica Acta, 2011, 56(5): 2599-2605.

【8】LUO Jian-yi, ZHOU Yang-yang, CHEN Run-ming, et al. Preparation of the high quality WO3 thin film and its application in the electrochromic digital display devuces[J]. Journal of Synthetic Crystals, 2013, 42: 124-128.
罗坚义, 周洋洋, 陈润明, 等. 高质量WO3薄膜的制备及其电致变色数码显示器件[J]. 人工晶体学报, 2013, 42: 124-128.

【9】RAO M C. Structure and properties of WO3 thin films for electrochromic device application[J]. Non-Oxide Glasses, 2013, 5: 1-8.

【10】CHENG X F , LENG W H , LIU D P , et al. Enhanced photoelectrocatalytic performance of Zn-doped WO3 photocatalysts for nitrite ions degradation under visible light[J]. Chemosphere, 2007, 68(10):1980-1984.

【11】CAI G F, TU J P, ZHOU D, et al. Dual electrochromic film based on WO3/polyaniline core/shell nanowire array[J]. Solar Energy Materials and Solar Cells, 2014, 122: 51-58.

【12】CAI G, WANG X, ZHOU D, et al. Hierarchical structure Ti-doped WO3 film with improved electrochromism in visible-infrared region[J]. Rsc Advances, 2013, 3(19): 6896-6905.

【13】BUCH V R, CHAWLA A K, RAWAL S K. Review on electrochromic property for WO3 thin films using different deposition techniques[J]. Materials Today: Proceedings, 2016, 3(6): 1429-1437.

【14】YAMAUCHI K , OCHIAI T , YAMAUCHI G . The synergistic antibacterial performance of a Cu/WO3-added PTFE particulate superhydrophobic composite material[J]. Journal of Biomaterials & Nanobiotechnology, 2012, 6(1):1-7.

【15】LIN B, LAN C, LI C, et al. Effect of thermal annealing on the performance of WO3-Ag-WO3 transparent conductive film[J]. Thin Solid Films, 2014, 571:134-138.

【16】SICHEL E K , GITTLEMAN J I , ZELEZ J . Electrochromism in the composite material Au-WO3[J]. Applied Physics Letters, 1977, 31(2):109-109.

【17】YIN Y, LAN C, GUO H, et al. Reactive sputter deposition of WO3/Ag/WO3 film for IndiumTin Oxide (ITO)-free electrochromic devices[J]. ACS Applied Materials & Interfaces, 2016, 8(6):3861-3867.

【18】LI H, LV Y, ZHANG X, et al. High-performance ITO-free electrochromic films based on bi-functional stacked WO3/Ag/WO3 structures[J]. Solar Energy Materials and Solar Cells, 2015, 136:86-91.

【19】KOUBLI E , TSAKANIKAS S , LEFTHERIOTIS G , et al. Optical properties and stability of near-optimum WO3/Ag/WO3 multilayers for electrochromic applications[J]. Solid State Ionics, 2015, 272:30-38.

【20】PANG Y, CHEN Q, SHEN X, et al. Size-controlled Ag nanoparticle modified WO3 composite films for adjustment of electrochromic properties[J]. Thin Solid Films, 2010, 518(8):1920-1924.

【21】李乐. WO3-Ag复合电致变色薄膜的制备与研究[D]. 成都: 电子科技大学, 2018.

【22】KHARADE R R , MALI S S , PATIL S P , et al. Enhanced electrochromic coloration in Ag nanoparticle decorated WO3 thin films[J]. Electrochimica Acta, 2013, 102:358-368.

【23】KADAM P M , TARWAL N L , SHINDE P S , et al. Enhanced optical modulation due to SPR in gold nanoparticles embedded WO3 thin films[J]. Journal of Alloys & Compounds, 2011, 509(5):0-1733.

【24】DOBSON, J P . Absorption and Scattering of Light by Small Particles[J]. Physics Bulletin, 1984, 35(3):104-104.

【25】ADHIKARI S, SARKAR D. High efficient electrochromic WO3 nanofibers[J]. Electrochimica Acta, 2014, 138: 115-123.

【26】NASERI N , KIM H , CHOI W , et al. Implementation of Ag nanoparticle incorporated WO3 thin film photoanode for hydrogen production[J]. International Journal of Hydrogen Energy, 2013, 38(5):2117-2125.

【27】LIU X, LIU Z, LU J, et al. Electrodeposition preparation of Ag nanoparticles loaded TiO2 nanotube arrays with enhanced photocatalytic performance[J]. Applied Surface Science, 2014, 288: 513-517.

引用该论文

MIAO Zhuang,YANG Xue,YANG Ji-kai,HOU Zhi-peng,ZHANG Yu-fei,WANG Xin,WANG Guo-zheng. Preparation and Electrochromic Properties of WO3/Ag Composite Film[J]. ACTA PHOTONICA SINICA, 2019, 48(10): 1031001

苗壮,杨雪,杨继凯,侯志鹏,张宇飞,王新,王国政. WO3/Ag复合薄膜的制备及其电致变色性能[J]. 光子学报, 2019, 48(10): 1031001

您的浏览器不支持PDF插件,请使用最新的(Chrome/Fire Fox等)浏览器.或者您还可以点击此处下载该论文PDF