Frontiers of Optoelectronics, 2019, 12 (4): 352–364, 网络出版: 2020-01-09  

Antimony doped Cs2SnCl6 with bright and stable

Antimony doped Cs2SnCl6 with bright and stable emission
作者单位
1 Wuhan National Laboratory for Optoelectronics (WNLO), Huazhong University of Science and Technology, Wuhan 430074, China
2 School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China
摘要
Abstract
Lead halide perovskites, with high photoluminescence efficiency and narrow-band emission, are promising materials for display and lighting. However, the lead toxicity and environmental sensitivity hinder their potential applications. Herein, a new antimony-doped lead-free inorganic perovskites variant Cs2SnCl6:xSb is designed and synthesized. The perovskite variant Cs2SnCl6:xSb exhibits a broadband orange-red emission, with a photoluminescence quantum yield (PLQY) of 37%. The photoluminescence of Cs2SnCl6:xSb is caused by the ionoluminescence of Sb3+ within Cs2SnCl6 matrix, which is verified by temperature dependent photoluminescence (PL) and PL decay measurements. In addition, the all inorganic structure renders Cs2SnCl6:xSb with excellent thermal and water stability. Finally, a white light-emitting diode (white-LED) is fabricated by assembling Cs2SnCl6:0.59%Sb, Cs2SnCl6:2.75%Bi and Ba2Sr2SiO4: Eu2+ onto the commercial UV LED chips, and the color rendering index (CRI) reaches 81.

Jinghui LI, Zhifang TAN, Manchen HU, Chao CHEN, Jiajun LUO, Shunran LI, Liang GAO, Zewen XIAO, Guangda NIU, Jiang TANG. Antimony doped Cs2SnCl6 with bright and stable[J]. Frontiers of Optoelectronics, 2019, 12(4): 352–364. Jinghui LI, Zhifang TAN, Manchen HU, Chao CHEN, Jiajun LUO, Shunran LI, Liang GAO, Zewen XIAO, Guangda NIU, Jiang TANG. Antimony doped Cs2SnCl6 with bright and stable emission[J]. Frontiers of Optoelectronics, 2019, 12(4): 352–364.

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!