大气与环境光学学报, 2013, 8 (6): 428, 网络出版: 2013-12-04
镧掺杂纳米二氧化钛透明光触媒乳液的制备及光催化性能
Preparation and Photocatalytic Properties of Transparent La-Doped Titanium Dioxide Photocatalyst Emulsion
摘要
以四氯化钛、草酸、氨水、硝酸镧、D-山梨醇等为主要的实验药品,采用了常温络合—控制水解法,制备出平 均粒径6.9 nm的镧掺杂纳米二氧化钛透明光触媒乳液。在太阳光照射下利用该透明乳液对酸性红3R染料 降解,并研究了染料初始浓度、样品加入量、体系pH值、加热回流时间对降解效果的影响。采用XRD、 纳米激光粒度分析仪、紫外—可见分光光度计等对样品的物相、粒径、组成、光吸收、光催化等性 质进行了表征。结果表明,当镧掺杂量为0.1%、体系pH值为6、回流时间为10 min时,镧掺杂纳米二氧化钛光 催化性能最好。太阳光照射60 min后,对浓度为25 mg/L的酸性红3R染料溶液的降解率达到98%以上。
Abstract
La-doped nano TiO2 colorless and transparent hydrosol with an average particle size of 6.9 nm was synthesized by a novel complexation-controlled hydrolysis method at room temperature by using TiCl4 , organic carboxylic acid, stabilizer, surfactant, NH3 ·H2 O, La(NO3 )3 ·6H2 O, and D-sorbitol etc as raw materials. And the acid red 3R was studied by the photocatalytic degradation. To study the effects of reflux time, pH and concentration and reaction conditions of the synthesis process and properties of the materials, the optimum preparation conditions were found out. The samples were characterized by X-ray diffraction (XRD), UV-visible spectroscopy (UV-Vis), and nano particle size analyzer. The La-doped nano-TiO2 transparent photocatalyst exhibits optimal photocatalytic performance when the doping content was 0.1% and the refluxing time was 10 min, respectively. The degradation efficiency of acid red 3R dye solution with concentration 25 mg/L has reached 98% after being exposed to sunlight for 60 min.
张文明, 李玲, 张华艳, 孙建红, 刘毅, 李晓苇, 傅广生. 镧掺杂纳米二氧化钛透明光触媒乳液的制备及光催化性能[J]. 大气与环境光学学报, 2013, 8(6): 428. ZHANG Wen-ming, LI Ling, ZHANG Hua-yan, SUN Jian-hong, LIU Yi, LI Xiao-wei, FU Guang-sheng. Preparation and Photocatalytic Properties of Transparent La-Doped Titanium Dioxide Photocatalyst Emulsion[J]. Journal of Atmospheric and Environmental Optics, 2013, 8(6): 428.