YxVO4∶0.01Dy3+ and Y0.99-xVO4∶0.01Dy3+, xBi3+ phosphors were synthesized by chemical co-precipitation method. Their crystal structure, micromorphology and photoluminescence (PL) properties were investigated by X-ray diffraction (XRD), scan electron microscopy (SEM) and spectrofluorometer. YxVO4∶0.01Dy3+ and Y0.99-xVO4∶0.01Dy3+, xBi3+ phosphors have a broad excitation band from about 250 to 350 nm including a strongest peak at about 310 nm. Under its excitation, the emission spectra exhibits two sharp peaks, one of which centered at about 483 nm for 4F9/2→6H15/2 transition of Dy3+ and the other at about 574 nm due to the 4F9/2→6H13/2 transition of Dy3+. For YxVO4∶0.01Dy3+ (x=0.94, 0.97, 0.99, 1.01, 1.03) phosphor, with increasing value of x, the body color of phosphor changes from yellow to white and the strongest peak in the excitation spectra shifts a little to shorter wavelength. It is detrimental to luminous intensity when Y3+ content deviates stoichiometric ratio. For Y0.99-xVO4∶0.01Dy3+, xBi3+ (x=0.01, 0.05, 0.1, 0.15, 0.2, 0.25) phosphor, the samples have extraneous bismuth vanadium oxide phase except for the major tetragonal zircon structure when x≥0.20. With increasing value of x, the band edge in the excitation spectra shifts to longer wavelength, the excitation intensity and luminous intensity increase early and decrease late. When the value of x is 0.01, the intensities increase evidently. In addition, the influence of Y3+ or Bi3+ on the color temperature of emission and micromorphology of YVO4∶Dy3+ is slight.