Author Affiliations
Abstract
1 Engineering Research Center of Micro-nano Optoelectronic Materials and Devices, Ministry of Education, Fujian Key Laboratory of Semiconductor Materials and Applications, College of Chemistry and Chemical Engineering, Pen-Tung Sah Institute of Micro-Nano Science and Technology, College of Physical Science and Technology, Xiamen University, Xiamen 361005, China
2 Xiamen Center for Disease Control and Prevention, Xiamen 361021, China
3 Xiamen Intelligent Health Research Institute, Xiamen 361009, China
4 School of Life Sciences, Xiamen University, Xiamen 361005, China
Deep-ultraviolet (DUV) disinfection technology provides an expeditious and efficient way to suppress the transmission of coronavirus disease 2019 (COVID-19). However, the influences of viral variants (Delta and Omicron) and low temperatures on the DUV virucidal efficacy are still unknown. Here, we developed a reliable and uniform planar light source comprised of 275-nm light-emitting diodes (LEDs) to investigate the effects of these two unknown factors and delineated the principle behind different disinfection performances. We found the lethal effect of DUV at the same radiation dose was reduced by the cryogenic environment, and a negative-U large-relaxation model was used to explain the difference in view of the photoelectronic nature. The chances were higher in the cryogenic environment for the capture of excited electrons within active genetic molecules back to the initial photo-ionised positions. Additionally, the variant of Omicron required a significantly higher DUV dose to achieve the same virucidal efficacy, and this was thanks to the genetic and proteinic characteristics of the Omicron. The findings in this study are important for human society using DUV disinfection in cold conditions (e.g., the food cold chain logistics and the open air in winter), and the relevant DUV disinfection suggestion against COVID-19 is provided.
LED UV-C III-nitrides semiconductors photoelectronic COVID-19 virucidal efficacy 
Opto-Electronic Advances
2023, 6(9): 220201
冯萧萧 1韩明宇 1陈美鹏 1方倩 1[ ... ]李欣 1,2,*
作者单位
摘要
1 南京邮电大学 通信与信息工程学院 江苏省氮化镓光电子集成国际合作联合实验室, 江苏 南京 210003
2 南京邮电大学 宽带无线通信与传感网技术教育部重点实验室, 江苏 南京 210003
在自然界中,物体运动无处不在,随着智能汽车、6G移动通信的高速发展,对通信和运动探测传感融合的高集成度通感一体器件的需求日益增加。本文基于氮化镓多量子阱结构发光和探测并存的特点,提出了一种基于蓝宝石衬底外延生长氮化镓多量子阱材料的集成式光电子芯片,该芯片具有灵敏的运动探测功能及可见光通信功能。该光电子芯片发射器向运动的目标物体发射蓝光波段可见光信号,经目标物体运动调制的可见光信号反射回光电子芯片的接收器部分,激发变化的光电流。通过分析接收器的光电流变化,可探测以不同速度旋转的目标物体的运动情况,光电流曲线变化周期与目标物体旋转周期一致。本文还研究了光电子芯片的各项光电指标及可见光通信性能,该芯片可用作可见光通信系统的收发终端,可以处理和传输芯片采集到的运动探测信号。基于氮化镓多量子阱材料的光电子芯片是一种具有实用价值的高集成度通感一体终端器件。
运动探测 多量子阱 三族氮化物 光电子芯片 可见光通信 motion detection multiple quantum wells III-nitride optoelectronic chips visible light communication 
中国光学
2023, 16(5): 1257
张永刚 1,2,*顾溢 1,2马英杰 1,2邵秀梅 1,2[ ... ]方家熊 1,2
作者单位
摘要
1 中国科学院上海技术物理研究所 传感技术国家重点实验室,上海 200083
2 中国科学院上海技术物理研究所 中国科学院红外成像材料与器件重点实验室,上海 200083
三五族化合物半导体具有丰富的特性,使其在电子学、光电子学以及光子学领域获得了各种应用,这些都源自于三族元素和五族元素构成之二元系的各种魔幻组合形成的多变特性。本文基于二元系砷化物、磷化物及锑化物,对其构成的各种三元系、四元系和五元系的特征进行了几何图示阐述,主要涉及其带隙、晶格常数及其与不同衬底的晶格匹配区域。对氮化物和稀氮、铋化物和稀铋以及硼化物的一些特性也进行了简要讨论。通过对整个三五族化合物半导体的全面了解将有助于深入了解其潜力和可持续发展态势,包括存在的诸多挑战。
三五族化合物半导体 二元系 三元系 四元系 五元系 III-V compound semiconductors binary ternary quaternary quinary 
红外与毫米波学报
2022, 41(6): 941
Author Affiliations
Abstract
Department of Chemistry and Biochemistry, Bard College, Annandale-on-Hudson, NY, United States of America
In this report, we demonstrate a novel technique for the microscopic patterning of gold by combining the photoreduction of AuIIIBr4 - to AuIBr2 - and the electrochemical reduction of AuIBr2 - to elemental gold in a single step within solution. While mask-based methods have been the norm for electroplating, the adoption of direct laser writing for flexible, real-time patterning has not been widespread. Through irradiation using a 405 nm laser and applying a voltage corresponding to a selective potential window specific to AuIBr2 -, we have shown that we can locally deposit elemental gold at the focal point of the laser. In addition to demonstrating the feasibility of the technique, we have collected data on the kinetics of the photoreduction reaction in ethanol and have deduced its rate law. We have confirmed the selective deposition of AuIBr2 - within a potential window through controlled potential electrolysis experiments and through direct measurement on a quartz crystal microbalance. Finally, we have verified local deposition through scanning electron microscopy.
photolithography direct laser writing electrodeposition gold (III) bromide photoreduction 
International Journal of Extreme Manufacturing
2022, 4(3): 035001
Author Affiliations
Abstract
1 Photonics Laboratory, Computer, Electrical and Mathematical Sciences and Engineering Division (CEMSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
2 Department of Electrical Engineering, Stanford University, Stanford, CA 94305, USA
3 Light Source Research Division, Korea Photonics Technology Institute (KOPTI), Gwangju 61007, Republic of Korea
4 School of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology, Gwangju 61005, Republic of Korea
5 Department of Advanced Convergence Technology, Research Institute of Advanced Convergence Technology, Korea Polytechnic University, 237 Sangidaehak-ro, Siheung-si 15073, Republic of Korea
6 King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
Epitaxially grown III-nitride alloys are tightly bonded materials with mixed covalent-ionic bonds. This tight bonding presents tremendous challenges in developing III-nitride membranes, even though semiconductor membranes can provide numerous advantages by removing thick, inflexible, and costly substrates. Herein, cavities with various sizes were introduced by overgrowing target layers, such as undoped GaN and green LEDs, on nanoporous templates prepared by electrochemical etching of n-type GaN. The large primary interfacial toughness was effectively reduced according to the design of the cavity density, and the overgrown target layers were then conveniently exfoliated by engineering tensile-stressed Ni layers. The resulting III-nitride membranes maintained high crystal quality even after exfoliation due to the use of GaN-based nanoporous templates with the same lattice constant. The microcavity-assisted crack propagation process developed for the current III-nitride membranes forms a universal process for developing various kinds of large-scale and high-quality semiconductor membranes.
III-nitride alloys membranes nanoporous Ni stressor light-emitting diodes ultraviolet photodetectors 
Opto-Electronic Science
2022, 1(10): 220016
石倩 1,2,3张书魁 2,3,*王建禄 2,3,4,5,**褚君浩 3,4
作者单位
摘要
1 中国科学院上海光学精密机械研究所,上海 201800
2 中国科学院大学杭州高等研究院 物理与光电工程学院,浙江 杭州 310024
3 中国科学院上海技术物理研究所 红外物理国家重点实验室,上海 200083
4 复旦大学 光电研究院 上海市智能光电与感知前沿科学研究基地,上海 200433
5 复旦大学 芯片与系统前沿技术研究院上海 200433
nBn红外探测器旨在消除肖特基-里德-霍尔产生复合电流,这将有效降低器件的暗电流并提高工作温度。由于制造工艺的兼容性和晶格匹配的衬底的存在,基于III-V化合物(包括二类超晶格材料)的nBn红外探测器得到了快速发展。通过理论模拟,基于HgCdTe材料的nBn红外探测器也能有效抑制暗电流。然而,去除价带势垒的困难阻碍了HgCdTe nBn器件的发展。本综述将阐述nBn探测器抑制暗电流的物理机制,并介绍nBn探测器在不同材料体系中的发展现状和趋势。
nBn红外探测器 Sb基III-V族半导体 二类超晶格 碲镉汞 nBn infrared detector Sb-based III-V semiconductor type-II superlattice HgCdTe 
红外与毫米波学报
2022, 41(1): 010
作者单位
摘要
辽宁工业大学 化学与环境工程学院, 交叉科学研究院, 锦州 121001
为去除水体中Cr(III)的污染, 本研究利用席夫碱反应原理制备了2-羟基-1-萘甲醛功能化SBA-15吸附剂(Q-SBA-15)。通过不同测试手段对所制备样品的形貌、孔道结构、元素组成和表面化学状态进行了系统表征。结果表明, SBA-15经2-羟基-1-萘甲醛修饰后, 其比表面积和孔径明显减小, 但表面形貌和晶体结构没有明显变化。为研究Q-SBA-15对Cr(III)的吸附性能, 详细分析了溶液pH和离子强度的影响, 以及吸附动力学、吸附等温线、吸附热力学和再生性能。结果表明, Q-SBA-15对Cr(III)吸附过程遵循准二级吸附动力学模型和Langmuir模型。当吸附温度为 40 ℃、pH为6、吸附时间为120 min时, Q-SBA-15对Cr(III)的吸附容量最大, 达到102.3 mg/g。Q-SBA-15对Cr(III)的吸附作用主要依靠其表面官能团与Cr(III)的配位螯合作用, 且为自发吸热过程。再生实验表明Q-SBA-15具有良好的重复使用性。该Q-SBA-15吸附剂在去除Cr(III)方面具有潜在的应用价值。
SBA-15 功能化 吸附 Cr(III) SBA-15 functionalization adsorption Cr(III) 
无机材料学报
2021, 36(11): 1163
Author Affiliations
Abstract
1 Institute for Solid State Physics and Optics Wigner Research Centre for Physics P.O. Box 49, H-1121 Budapest, Hungary
2 Institute of Physics, University of Szeged Dom ter 9, H-6720 Szeged, Hungary
3 Ministry of Higher Education and Scientific Research Baghdad 10065, Iraq
4 Physiology Department, College of Medicine University of Misan, Al-Amarah, Misan 62001, Iraq
5 Uzhhorod National University, Uzhhorod 88015 Transcarpathia, Ukraine
6 Science Medical Center, Saratov State University 83 Astrakhanskaya Str., Saratov 410012, Russia
7 Optoelectronics and Measurement Techniques Laboratory University of Oulu, 90570 Oulu, Finland
8 Laboratory of Laser Diagnostics of Technical and Living Systems Institute of Precision Mechanics and Control of the Russian Academy of Sciences 24 Rabochaya, Saratov 410028, Russia
9 Interdisciplinary Laboratory of Biophotonics National Research Tomsk State University 36 Lenin Avenue, Tomsk 634050, Russia
Confocal Raman microspectroscopy (CRM) with 633- and 785-nm excitation wavelengths combined with optical clearing (OC) technique was used for ex-vivo study of porcine skin in the Raman fingerprint region. The optical clearing has been performed on the skin samples by applying a mixture of glycerol and distilled water and a mixture of glycerol, distilled water and chemical penetration enhancer dimethyl sulfoxide (DMSO) during 30 min and 60 min of treatment. It was shown that the combined use of the optical clearing technique and CRM at 633nm allowed one to preserve the high probing depth, signal-to-noise ratio and spectral resolution simultaneously. Comparing the effect of different optical clearing agents on porcine skin showed that an optical clearing agent containing chemical penetration enhancer provides higher optical clearing efficiency. Also, an increase in treatment time allows to improve the optical clearing efficiency of both optical clearing agents. As a result of optical clearing, the detection of the amide-III spectral region indicating well-distinguishable structural differences between the type-I and type-IV collagens has been improved.
CRM skin collagen types I and IV amide III tissue optical clearing glycerol DMSO 
Journal of Innovative Optical Health Sciences
2021, 14(5): 2142003
作者单位
摘要
1 1.华北理工大学 化学工程学院, 河北省环境光电催化材料重点实验室, 唐山 063210
2 2.唐山中地地质工程有限公司, 唐山 063009
3 3.河北省地矿局第二地质大队, 唐山 063009

光催化-芬顿技术耦合可高效降解有机污染物。本研究采用溶剂热法制备了Fe(III)掺杂rGO/Bi2MoO6复合催化剂(Fe(III)/rGO/Bi2MoO6), 通过外加H2O2构建了光催化-芬顿协同体系, 可见光照射3 h后对苯酚的降解率(82%)远高于单独光催化(18%)或芬顿反应(48%), 进一步优化条件对苯酚可实现完全降解。这主要是通过Fe得失电子实现价态的转变, 并以此作为桥梁实现光催化-芬顿的协同作用。同时石墨烯的优异导电性能不仅克服了光催化中光生电子空穴难以分离的问题, 而且促进了Fe3+/Fe2+的循环反应, 促使芬顿反应产生更多的羟基自由基(•OH), 进一步提高了苯酚的降解效率。实验考察了Fe(III)含量、催化剂投加量、H2O2含量以及pH等因素对协同降解效果的影响。淬灭实验证明•OH是协同降解体系中最主要的活性物种, •O2-和h+对降解活性也会产生一定的影响, 结合实验结果提出了Fe(III)/rGO/Bi2MoO6光催化-芬顿协同降解苯酚的机理。

Fe(III)/rGO/Bi2MoO6 光催化-芬顿 协同 降解 Fe(III)/rGO/Bi2MoO6 photocatalysis-Fenton synergy degradation 
无机材料学报
2021, 36(6): 615
Author Affiliations
Abstract
Hewlett Packard Labs, Hewlett Packard Enterprise, 820 N McCarthy Blvd, Milpitas, CA 95035, USA
In many application scenarios, silicon (Si) photonics favors the integration of III-V gain material onto Si substrate to realize the on-chip light source. In addition to the current popular integration approaches of III-V-on-Si wafer bonding or direct heteroepitaxial growth, a newly emerged promising solution of epitaxial regrowth on bonded substrate has attracted a lot of interests. High-quality III-V material realization and successful laser demonstrations show its great potential to be a promising integration platform for low-cost, high-integration density and highly scalable active-passive photonic integration on Si. This paper reviews recent research work on this regrowth on bonded template platform including template developments, regrown material characterizations and laser demonstrations. The potential advantages, opportunities and challenges of this approach are discussed.
Si photonics III-V-on-Si laser photonic integration epitaxy regrowth 
Opto-Electronic Advances
2021, 4(9): 09200094

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