布洛赫表面波（BSW）是光场局域在光子晶体表面层并沿着表面传播的一种电磁模式。本文在一维光子晶体上制备了PS∶C545T有机发光层，观察到了有机小分子C545T的激子耦合进BSW模式的荧光。通过对半球透镜耦合输出光斑的发光性能研究，分析比较了C545T的常规发光和BSW模式发光的不同特点。结果表明，BSW模式耦合输出环形的光斑，其荧光具有很窄的空间分布、线偏振和光谱角度可调的特性，并与常规辐射模式的光斑明显分离。一维光子晶体上的发光薄膜的辐射跃迁速率存在各向异性的现象，其中BSW模式的荧光具有更快的辐射跃迁速率。利用BSW的上述发光特点有助于开发具有一定方向性的偏振发光器件。

纯有机室温磷光材料因其成本低廉和性能易调控等优点，成为目前功能材料领域研究的热点。本文详细介绍了近年来纯有机室温磷光材料的发展，系统归纳了纯有机小分子晶体、聚合物和智能响应的室温磷光材料进展，并总结了在室温大气环境下实现有机室温磷光的有效策略。

In order to realize single emissive white phosphorescent organic light-emitting devices (PHOLEDs) with three color phosphorescent dopants (red, green, and blue), the energy transfer between the host material and the three dopants, as well as the among the three dopants themselves, should be considered and optimized. To explore the effect of red phosphorescent dopant on the color rendering index (CRI), the authors investigate the wavelength position of the maximum emission peak from three phosphorescent dopants. The CRI and luminous efficiency of white PHOLED in which Ir(pq)2(acac) acts as the red phosphorescent dopant are found to be greater than those of devices prepared using Ir(piq)3 and Ir(btp)2(acac) as the emission spectrum has a relatively high intensity near the human perception of blue, red, and green wavelengths. Furthermore, we demonstrate that the performance of the three dopants is related to the absorption characteristics of the red phosphorescent dopant. With a maximum emission peak at 600 nm, Ir(pq)2(acac) has a higher intensity in the concave section between 550 and 600 nm seen for red and blue dopants. In addition, the long metal-to-ligand charge transfer (MLCT) absorption tail of Ir(pq)2(acac) overlaps with the emission spectra of the green dopant, enhancing emission. Such energy transfer mechanisms are confirmed to optimize white emission in the single emissive white PHOLEDs.

Lanthanide-doped polymers are very attractive, since they can be used for luminescent optical fiber fabrications. This Letter presents the terbium-ions-doped poly(methyl methacrylate) fiber fabrication and spectroscopic characterization. The measured excited state (D45) lifetime of 0.741 ms confirms that a used organometallic can be used to obtain an intense luminescence in a polymeric fiber. The luminescence spectrum shape modification versus the fiber length is also investigated.

The optical constants, photoluminescence properties, and resistivity of Al-Alq3 thin films prepared by the thermal co-evaporation method on a silicon substrate are studied with various Al fractions. A variable angle spectroscopic ellipsometry is employed to determine the optical constants in the wavelength from 300 to 1200 nm at incidence angles of 65°, 70°, and 75°, respectively. Both the refractive indices and extinction coefficient apparently increase with increasing Al fractions. The intensity of photoluminescence spectra gradually increases with decreasing Al fractions due to intrinsic energy level transition of Alq3 organic semiconductor in the ultraviolet wave band. The resistivity decreases from 42.1 to 3.36 Ω·cm with increasing Al fraction from 40% to 70%, resulting in a larger emission intensity in photoluminescence spectra for the 40% Al fraction sample.

This Letter presents the fabrication and characterization of a perylene (Per) and Rhodamine 6 G (Rh 6 G) co-doped polymeric fiber. The spectroscopic properties (luminescence spectra, attenuation, energy transfer) of the co-doped polymethyl methacrylate (PMMA) fiber are presented. Two different concentrations of Rh 6 G (2.2×10 4 and 4.1×10 4 mol/L) and a constant Per concentration (6.2×10 4 mol/L) are used in the experiments. The luminescence spectrum changes versus the fiber length are discussed. Additionally, the ratio of the maximum fluorescence peaks of the used dyes is calculated versus the fiber length. The obtained results show the energy transfer from Per (donor) to Rh 6 G (acceptor). The proposed co-doped fiber can be used in applications in lighting and sensor technology.

Two kinds of novel blue-emitting materials, anthracene-based derivatives, are synthesized by the Suzuki coupling reaction. It is worth noting that the maximum emission wavelengths of the two materials are 441 and 444 nm in tetrahydrofuran and 456 and 454 nm in film states, which are the typical blue fluorescence and the fluorescence quantum yields of them are 0.87 and 1.12 by using 9,10-diphenylanthracene (Φf=0.90) as a calibration standard. The full width at half maximum of them are 56, 55 nm in solution, respectively, presenting good color purity. Both of them display superior thermal properties and electrochemical properties. Scanning electronic microscope results show that the films of two compounds are continuous, compact, and smooth after 100°C for 3 h. These data indicate their potential to be prepared for high efficiency and long operation lifetime organic light-emitting diodes devices.

In this Letter, temporal self-modifying behavior of amplitude modulation pulse propagation characteristics in multiphoton absorbers is presented by solving the underlying theoretical model coupling the propagation equation with the rate equations. The characteristics of the output temporal shapes are of primary concern and are discussed in detail. Amplitude modulation suppressing effects of multiphoton absorbers are numerically demonstrated; they have not been reported previously, to our knowledge. By taking a time resolved absorption coefficients, the corresponding physical mechanism is explicitly interpreted.