1 国网智能电网研究院有限公司, 北京102209
2 2.国网公司电力智能传感技术实验室,北京102209
3 国网北京电力科学研究院,北京100075
4 4.现场检测技术标准验证实验室,北京102209
5 国网智能电网研究院有限公司, 北京102209河北工业大学 机械工程学院,天津 300401
提出了一种利用铁电偶极子提高摩擦发电机表面电荷密度的方法。利用聚偏氟乙烯(PVDF)的铁电特性,在摩擦电层形成正电荷陷阱,增强摩擦电材料的发电性能,从而提高摩擦电纳米发电机的表面电荷密度。采用铸造工艺和单轴拉伸工艺制备了PVDF薄膜,并将其集成到具有垂直分离结构的摩擦电纳米发电机中。系统地研究了PVDF膜的埋置方向、厚度和极化强度对摩擦纳米发电机输出功率的影响。结果表明,当压电膜厚度为100 μm,最大极化电场为90 MV/m时,摩擦电纳米发电机的峰值功率提高了2.6倍。这项工作为调节摩擦电纳米发电机的性能提供了新的见解。The Influence of Ferroelectric Dipoles on the Output Performance of Triboelectric
多功能复合材料 薄膜 电气性能 摩擦纳米发电机 multifunctional composites thin films electrical properties triboelectric nanogenerator
Author Affiliations
Abstract
State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 611731, P. R. China
High entropy oxides (HEO) are single-phase solid solutions which are formed by the incorporation of five or more elements into a cationic sublattice in equal or near-equal atomic proportions. Its unique structural features and the possibility of targeted access to certain functions have attracted great interest from researchers. In this review, we summarize the recent advances in the electronic field of high-entropy oxides. We emphasize the following three fundamental aspects of high-entropy oxides: (1) The conductivity mechanism of metal oxides; (2) the factors affecting the formation of single-phase oxides; and (3) the electrical properties and applications of high-entropy oxides. The purpose of this review is to provide new directions for designing and tailoring the functional properties of relevant electronic materials via a comprehensive overview of the literature on the field of high-entropy oxide electrical properties.
High entropy dielectrics conductive mechanisms electrical properties dielectric constant Journal of Advanced Dielectrics
2023, 13(5): 2350014
Author Affiliations
Abstract
1 Zhejiang Provincial Engineering Research Center of Energy Optoelectronic Materials and Devices, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
2 The Faculty of Information Science and Engineering, Ningbo University, Ningbo 315211, China
3 Zhejiang Provincial Key Laboratory of Power Semiconductor Materials and Devices, ZJU-Hangzhou Global Scientific and Technological Innovation Center, Hangzhou 311200, China
4 Yongjiang Laboratory, Ningbo 315201, China
This study explores the epitaxial relationship and electrical properties of α-Ga2O3 thin films deposited on a-plane, m-plane, and r-plane sapphire substrates. We characterize the thin films by X-ray diffraction and Raman spectroscopy, and elucidate thin film epitaxial relationships with the underlying sapphire substrates. The oxygen vacancy concentration of α-Ga2O3 thin films on m-plane and r-plane sapphire substrates are higher than α-Ga2O3 thin film on a-plane sapphire substrates. All three thin films have a high transmission of over 80% in the visible and near-ultraviolet regions, and their optical bandgaps stay around 5.02–5.16 eV. Hall measurements show that the α-Ga2O3 thin film grown on r-plane sapphire has the highest conductivity of 2.71 S/cm, which is at least 90 times higher than the film on a-plane sapphire. A similar orientation-dependence is seen in their activation energy as revealed by temperature-dependent conductivity measurements, with 0.266, 0.079, and 0.075 eV for the film on a-, m-, r-plane, respectively. The origin of the distinct transport behavior of films on differently oriented substrates is suggested to relate with the distinct evolution of oxygen vacancies at differently oriented substrates. This study provides insights for the substrate selection when growing α-Ga2O3 films with tunable transport properties.
gallium oxide thin film epitaxy orientation oxygen vacancy electrical properties Journal of Semiconductors
2023, 44(6): 062802
Siyi Huang 1,2,3Masao Ikeda 2,3,*Minglong Zhang 1,2,3Jianjun Zhu 2,3Jianping Liu 1,2,3,**
Author Affiliations
Abstract
1 School of Nano-Tech and Nano-Bionics, University of Science and Technology of China, Hefei 230026, China
2 Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China
3 Key Laboratory of Nanodevices and Applications, Chinese Academy of Sciences, Suzhou 215123, China
A suitable contacting scheme for p-(Al)GaN facilitating quick feedback and accurate measurements is proposed in this study. 22 nm p+-GaN followed by 2 nm p-In0.2Ga0.8N was grown on p-type layers by metal-organic chemical vapor deposition. Samples were then cut into squares after annealing and contact electrodes using In balls were put at the corners of the squares. Good linearity between all the electrodes was confirmed inI–V curves during Hall measurements even with In metal. Serval samples taken from the same wafer showed small standard deviation of ~ 4% for resistivity, Hall mobility and hole concentration. The influence of contact layer on the electrical characteristics of bulk p-type layers was then investigated by step etching technique using inductively coupled plasma etching and subsequent Hall-effect measurements. Identical values could be obtained consistently when a 28 nm non-conductive layer thickness at the surface was taken into account. Therefore, the procedures for evaluating the electrical properties of GaN-based p-type layers just using In balls proposed in this study are shown to be quick and useful as for the other conventional III–V materials.
GaN electrical properties ohmic contact Journal of Semiconductors
2023, 44(5): 052802
Author Affiliations
Abstract
1 Key Laboratory of Materials for High Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
2 Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
3 Hangzhou Institute of Optics and Fine Mechanics, Hangzhou 311421, China
Sb-doped crystals were grown using the optical floating zone (OFZ) method. X-ray diffraction data and X-ray rocking curves were obtained, and the results revealed that the Sb-doped single crystals were of high quality. Raman spectra revealed that Sb substituted Ga mainly in the octahedral lattice. The carrier concentration of the Sb-doped single crystals increased from to , the electronic mobility depicted a decreasing trend from to , and the electrical resistivity varied from 0.603 to 0.017 ·cm with the increasing Sb doping concentration. The un-doped and Sb-doped crystals exhibited good light transmittance in the visible region; however, the evident decrease in the infrared region was caused by increase in the carrier concentration. The Sb-doped single crystals had high transmittance in the UV region as well, and the cutoff edge appeared at 258 nm.
Sb-doped β-Ga2O3 crystal growth optical properties electrical properties Chinese Optics Letters
2023, 21(4): 041605
1 中国科学院上海硅酸盐研究所,上海 200050
2 中国科学院大学,北京 100864
压电材料是一类极其重要的功能材料,利用其正/逆压电效应可以制成压电传感器、换能器和驱动器等,在航空航天、核能、医疗等领域有广泛应用。在航天、核能等领域,压电材料面临高辐射的严苛服役环境,对压电材料的抗辐射能力提出了更高要求。本文总结了辐射对钙钛矿结构包括锆钛酸铅[Pb(Zr, Ti)O3]、铌酸钾(KNbO3)、钛酸钡(BaTiO3)和以及铋层状结构压电材料如Bi4Ti3O12等的晶体结构和电学性能的影响。研究表明,在高剂量辐射下,压电材料的相结构维持在铁电相,但是晶粒一定程度上会受到破坏,同时压电材料的电学性能普遍随着辐射剂量的增强而减弱,但辐射也可以改善压电材料的抗疲劳性能,理论上辐射可以作为压电材料改性的一种方式。
压电材料 辐射 晶体结构 电学性能 piezoelectric materials radiation crystal structure electrical properties
光子学报
2022, 51(12): 1212003
1 中南大学 粉末冶金研究院 湖南 长沙 410083
2 空间智能机器人系统技术与应用北京市重点实验室 北京空间飞行器总体设计部, 北京 100094
3 中南大学 化学与化工学院, 湖南 长沙 410083
3-3型压电复合材料在超声波传感器、水下声学检测等领域有着广泛的应用。锆钛酸铅(PZT)陶瓷通过复合有望制备具有低介电常数、低脆性等优点的复合材料。采用直写成型技术制备了PZT三维木堆结构支架, 结合浸渍法填充环氧树脂制备了3-3型PZT/环氧树脂压电复合材料。研究了陶瓷相体积分数对3-3型PZT/环氧树脂压电复合材料的介电、压电、铁电性能的影响, 并对比了PZT陶瓷支架与PZT/环氧树脂复合材料的介电与压电性能。研究结果表明, 随着陶瓷相体积分数的增加, 复合材料的介电常数、压电常数及剩余极化强度都会增大, PZT支架具有更大的介电常数、压电常数、压电电压常数; 当陶瓷相体积分数为36%时, PZT支架与PZT/环氧树脂的压电电压常数分别达到151.0 mV·m/N与104.0 mV ·m/N。PZT/环氧树脂复合材料同时具备了压电陶瓷的硬度、电性能, 以及聚合物的柔韧性、低密度等优势, 其应用前景良好。
压电复合材料 直写成型 锆钛酸铅 3-3型 电性能 piezoelectric composites direct ink writing lead zirconate titanate 3-3 type electrical properties
1 天津职业技术师范大学 汽车与交通学院, 天津 300222
2 天津大学 微电子学院, 天津 300072
利用旋涂银纳米线和磁控溅射ZnSnO薄膜相结合的方法, 实现了高性能ZnSnO/AgNW双层透明电极的制备。采用X射线衍射仪和扫描电子显微镜对电极的结构和形貌进行了表征分析, 利用紫外可见分光光度计和四探针测试仪分别对ZnSnO/AgNW双层透明电极的电学和光学性能进行了表征。结果表明, 制备的ZnSnO/AgNW双层透明电极具有优异的电学和光学性能, 在透过率为88.1%时, 其方阻为12.3Ω/□, 品质因子高达231。在5.0mm的曲率半径下, 对ZnSnO/AgNW双层透明电极进行了1000次弯曲测试, 其电阻仅增加了13%, 表明ZnSnO/AgNW双层透明电极具有优异的柔性性能。此外, ZnSnO/AgNW双层透明电极经过20次胶带粘附测试和高温高湿测试后, 方阻都基本保持不变, 这说明ZnSnO/AgNW双层透明电极具有优异的粘附性以及抗氧化性。
透明导电 柔性 薄膜 纳米线 电学性能 transparent conductive flexible thin films nanowire electrical properties
吉林大学 物理学院 超硬材料国家重点实验室, 长春 130012
二维金刚石是具有独特物理特性的原子级厚度超薄金刚石纳米膜,同时具备体金刚石的多种优异性质。目前,关于二维金刚石的研究尚处于初始阶段,主要集中于结构和电学性能的理论工作,近年来开始有实验制备相关报道。文章介绍了二维金刚石的最新进展,重点讨论了结构、表面功能调制和电学特性的理论和实验结果,及其发展趋势、面临的挑战和应用前景。
二维金刚石 表面重构 表面功能化 电学性质 twodimensional diamond surface reconstruction surface functionalization electrical properties